NAOC Open IR
A systematic spectroscopic study of laboratory synthesized manganese oxides relevant to Mars
Xin, Yanqing1,2; Cao, Haijun1; Liu, Changqing1; Chen, Jian1; Liu, Ping1; Lu, Yingbo1; Ling, Zongcheng1,3
2021-08-15
Source PublicationJOURNAL OF RAMAN SPECTROSCOPY
ISSN0377-0486
Pages16
AbstractMn-rich minerals have been found by Mars rovers Curiosity and Opportunity in multiple sedimentary and basaltic outcrops at Gale and Endeavour craters, respectively, though the exact Mn-bearing mineral species and the related geologic processes still need to be confirmed and elucidated. In the Kimberley region at Gale Crater, the Mn content of fracture-filling materials that crosscut sandstone was evaluated to be higher than 25 wt%, indicating the existence of Mn oxides rather than evaporites or other salts. Furthermore, hydrated manganese oxides were also observed in Martian breccia meteorites Northwest Africa 7034 and 7533. However, due to the chemical complexities and often poor crystallinity of Mn-oxide group, there are still difficulties for the quick and accurate phase identification by any single spectroscopic method. In this work, we focus on the systematic spectroscopic studies of seven pure Mn oxides (alpha-MnO2, beta-MnO2, gamma-MnO2, delta-MnO2, alpha-Mn2O3, alpha-Mn3O4, gamma-MnOOH) synthesized in laboratory, which were grown using a set of hydrothermal reaction and solid-state calcination methods. Scanning electron microscope (SEM), energy-dispersive spectrometer (EDS), and laser-induced breakdown spectroscopy (LIBS) were used to obtain the morphology and chemical compositions. X-ray diffraction (XRD) was employed for the phase identification and structural characterization of Mn oxides. Various spectroscopic techniques such as Raman, mid-infrared (MIR), and visible and near-infrared (VNIR) were used to demonstrate their spectral characteristics. We thus established a diverse spectral library including Raman, MIR, VNIR, and LIBS datasets of Mn oxides, facilitating for the phase identifications of Mn-bearing minerals for future applications in Mars explorations missions (e.g., Tianwen-1 orbiter and Zhurong rover and Perseverance rover) as well as terrestrial and other planetary explorations.
Keywordlaboratory synthesis manganese oxides Mars phase identification Raman
Funding OrganizationChina Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; Key Laboratory of Space Active Opto-electronics Technology, Chinese Academy of Sciences ; Key Laboratory of Space Active Opto-electronics Technology, Chinese Academy of Sciences ; Key Laboratory of Lunar and Deep Space Exploration, Chinese Academy of Sciences ; Key Laboratory of Lunar and Deep Space Exploration, Chinese Academy of Sciences ; Natural Science Foundation of Shandong Province ; Natural Science Foundation of Shandong Province ; Pre-research project on Civil Aerospace Technologies of China National Space Administration ; Pre-research project on Civil Aerospace Technologies of China National Space Administration ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Physical-Chemical Materials Analytical & Testing Center of Shandong University at Weihai ; Physical-Chemical Materials Analytical & Testing Center of Shandong University at Weihai ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; Key Laboratory of Space Active Opto-electronics Technology, Chinese Academy of Sciences ; Key Laboratory of Space Active Opto-electronics Technology, Chinese Academy of Sciences ; Key Laboratory of Lunar and Deep Space Exploration, Chinese Academy of Sciences ; Key Laboratory of Lunar and Deep Space Exploration, Chinese Academy of Sciences ; Natural Science Foundation of Shandong Province ; Natural Science Foundation of Shandong Province ; Pre-research project on Civil Aerospace Technologies of China National Space Administration ; Pre-research project on Civil Aerospace Technologies of China National Space Administration ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Physical-Chemical Materials Analytical & Testing Center of Shandong University at Weihai ; Physical-Chemical Materials Analytical & Testing Center of Shandong University at Weihai ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; Key Laboratory of Space Active Opto-electronics Technology, Chinese Academy of Sciences ; Key Laboratory of Space Active Opto-electronics Technology, Chinese Academy of Sciences ; Key Laboratory of Lunar and Deep Space Exploration, Chinese Academy of Sciences ; Key Laboratory of Lunar and Deep Space Exploration, Chinese Academy of Sciences ; Natural Science Foundation of Shandong Province ; Natural Science Foundation of Shandong Province ; Pre-research project on Civil Aerospace Technologies of China National Space Administration ; Pre-research project on Civil Aerospace Technologies of China National Space Administration ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Physical-Chemical Materials Analytical & Testing Center of Shandong University at Weihai ; Physical-Chemical Materials Analytical & Testing Center of Shandong University at Weihai ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; Key Laboratory of Space Active Opto-electronics Technology, Chinese Academy of Sciences ; Key Laboratory of Space Active Opto-electronics Technology, Chinese Academy of Sciences ; Key Laboratory of Lunar and Deep Space Exploration, Chinese Academy of Sciences ; Key Laboratory of Lunar and Deep Space Exploration, Chinese Academy of Sciences ; Natural Science Foundation of Shandong Province ; Natural Science Foundation of Shandong Province ; Pre-research project on Civil Aerospace Technologies of China National Space Administration ; Pre-research project on Civil Aerospace Technologies of China National Space Administration ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Physical-Chemical Materials Analytical & Testing Center of Shandong University at Weihai ; Physical-Chemical Materials Analytical & Testing Center of Shandong University at Weihai
DOI10.1002/jrs.6231
WOS KeywordHYDROTHERMAL SYNTHESIS ; RAMAN-SPECTRA ; OXIDATION CATALYSIS ; WATER OXIDATION ; GALE CRATER ; GAMMA-MNO2 ; ALPHA-MNO2 ; BIRNESSITE ; ROVER ; MORPHOLOGIES
Language英语
Funding ProjectChina Postdoctoral Science Foundation[2020M682164] ; Key Laboratory of Space Active Opto-electronics Technology, Chinese Academy of Sciences[2018-ZDKF-2] ; Key Laboratory of Lunar and Deep Space Exploration, Chinese Academy of Sciences[LDSE202002] ; Natural Science Foundation of Shandong Province[ZR2019MD008] ; Pre-research project on Civil Aerospace Technologies of China National Space Administration[D020102] ; National Natural Science Foundation of China[11941001] ; National Natural Science Foundation of China[41972322] ; National Natural Science Foundation of China[U1931211] ; Physical-Chemical Materials Analytical & Testing Center of Shandong University at Weihai
Funding OrganizationChina Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; Key Laboratory of Space Active Opto-electronics Technology, Chinese Academy of Sciences ; Key Laboratory of Space Active Opto-electronics Technology, Chinese Academy of Sciences ; Key Laboratory of Lunar and Deep Space Exploration, Chinese Academy of Sciences ; Key Laboratory of Lunar and Deep Space Exploration, Chinese Academy of Sciences ; Natural Science Foundation of Shandong Province ; Natural Science Foundation of Shandong Province ; Pre-research project on Civil Aerospace Technologies of China National Space Administration ; Pre-research project on Civil Aerospace Technologies of China National Space Administration ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Physical-Chemical Materials Analytical & Testing Center of Shandong University at Weihai ; Physical-Chemical Materials Analytical & Testing Center of Shandong University at Weihai ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; Key Laboratory of Space Active Opto-electronics Technology, Chinese Academy of Sciences ; Key Laboratory of Space Active Opto-electronics Technology, Chinese Academy of Sciences ; Key Laboratory of Lunar and Deep Space Exploration, Chinese Academy of Sciences ; Key Laboratory of Lunar and Deep Space Exploration, Chinese Academy of Sciences ; Natural Science Foundation of Shandong Province ; Natural Science Foundation of Shandong Province ; Pre-research project on Civil Aerospace Technologies of China National Space Administration ; Pre-research project on Civil Aerospace Technologies of China National Space Administration ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Physical-Chemical Materials Analytical & Testing Center of Shandong University at Weihai ; Physical-Chemical Materials Analytical & Testing Center of Shandong University at Weihai ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; Key Laboratory of Space Active Opto-electronics Technology, Chinese Academy of Sciences ; Key Laboratory of Space Active Opto-electronics Technology, Chinese Academy of Sciences ; Key Laboratory of Lunar and Deep Space Exploration, Chinese Academy of Sciences ; Key Laboratory of Lunar and Deep Space Exploration, Chinese Academy of Sciences ; Natural Science Foundation of Shandong Province ; Natural Science Foundation of Shandong Province ; Pre-research project on Civil Aerospace Technologies of China National Space Administration ; Pre-research project on Civil Aerospace Technologies of China National Space Administration ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Physical-Chemical Materials Analytical & Testing Center of Shandong University at Weihai ; Physical-Chemical Materials Analytical & Testing Center of Shandong University at Weihai ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; Key Laboratory of Space Active Opto-electronics Technology, Chinese Academy of Sciences ; Key Laboratory of Space Active Opto-electronics Technology, Chinese Academy of Sciences ; Key Laboratory of Lunar and Deep Space Exploration, Chinese Academy of Sciences ; Key Laboratory of Lunar and Deep Space Exploration, Chinese Academy of Sciences ; Natural Science Foundation of Shandong Province ; Natural Science Foundation of Shandong Province ; Pre-research project on Civil Aerospace Technologies of China National Space Administration ; Pre-research project on Civil Aerospace Technologies of China National Space Administration ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Physical-Chemical Materials Analytical & Testing Center of Shandong University at Weihai ; Physical-Chemical Materials Analytical & Testing Center of Shandong University at Weihai
WOS Research AreaSpectroscopy
WOS SubjectSpectroscopy
WOS IDWOS:000684945600001
PublisherWILEY
Citation statistics
Document Type期刊论文
Identifierhttp://ir.bao.ac.cn/handle/114a11/76123
Collection中国科学院国家天文台
Corresponding AuthorLing, Zongcheng
Affiliation1.Shandong Univ, Shandong Key Lab Opt Astron & Solar Terr, Sch Space Sci & Phys, Inst Space Sci, 180 Wenhua Xilu, Weihai 264209, Peoples R China
2.Chinese Acad Sci, Key Lab Lunar & Deep Space Explorat, Natl Astron Observ, Beijing, Peoples R China
3.Chinese Acad Sci, Key Lab Space Act Optoelect Technol, Shanghai, Peoples R China
Recommended Citation
GB/T 7714
Xin, Yanqing,Cao, Haijun,Liu, Changqing,et al. A systematic spectroscopic study of laboratory synthesized manganese oxides relevant to Mars[J]. JOURNAL OF RAMAN SPECTROSCOPY,2021:16.
APA Xin, Yanqing.,Cao, Haijun.,Liu, Changqing.,Chen, Jian.,Liu, Ping.,...&Ling, Zongcheng.(2021).A systematic spectroscopic study of laboratory synthesized manganese oxides relevant to Mars.JOURNAL OF RAMAN SPECTROSCOPY,16.
MLA Xin, Yanqing,et al."A systematic spectroscopic study of laboratory synthesized manganese oxides relevant to Mars".JOURNAL OF RAMAN SPECTROSCOPY (2021):16.
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